Oppositely Charged Ti3C2Tx MXene Membranes with 2D Nanofluidic Channels for Osmotic Energy Harvesting.

Oppositely Charged Ti3C2Tx MXene Membranes with 2D Nanofluidic Channels for Osmotic Energy Harvesting. Angew Chem Int Ed Engl. 2020 Jan 16;: Authors: Ding L, Xiao D, Lu Z, Deng J, Wei Y, Caro J, Wang H Abstract Membrane-based reverse electrodialysis (RED) is considered as the most promising technique to harvest osmotic energy. However, the traditional membranes are limited by the high internal resistance and low efficiency, resulting in undesirable power densities. Here, we report the combination of oppositely charged Ti 3 C 2 T x MXene membranes (MXMs) with confined 2D nanofluidic channels as high-performance osmotic power generators. The negatively or positively charged 2D MXene nanochannels exhibit typical surface-charge-governed ion transport and show excellent cation or anion selectivity. By mixing the artificial sea water (0.5 M NaCl) and river water (0.01 M NaCl), we obtain a maximum power density of ~4.6 W m -2 , higher than most of the state-of-the-art membrane-based osmotic power generators, and very close to the commercialization benchmark (5 W m -2 ). Through connecting ten tandem MXM-RED stacks, the output voltage can reach up 1.66 V, which can directly power the electronic devices. This work significantly expands possibilities for the application of MXMs in osmotic power generation, making this blue energy a tangible and promising alternative. PMID: 31950586 [PubMed - as supplied by publisher]
Source: Angewandte Chemie - Category: Chemistry Authors: Tags: Angew Chem Int Ed Engl Source Type: research