Homocoupling of CO and isocyanide mediated by a C,C ’-bis(silylenyl)- substituted ortho-carborane

This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Matthias Driess, Shenglai Yao, Yun Xiong, Tibor Szilvasi, Ale š Růžička The unexpected reactivity of the o-carborane supported bis-silylene [(LSi:)C]2B10H10 1 {L= PhC(tBuN)2} towards carbon monoxide and 2,6-dimethylphenyl isocyanide is reported. While the reaction of 1 with CO leads selectively to... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - Category: Chemistry Authors: Source Type: research

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Publication date: Available online 24 January 2020Source: Catalysis TodayAuthor(s): Jack H. Baricuatro, Youn-Geun Kim, Carol L. Korzeniewski, Manuel P. SoriagaABSTRACTThe first isolable intermediate in the electrochemical reduction of carbon dioxide is carbon monoxide. This species, or its hydrated form, formic acid, is also the primary end product from all but a handful of metallic electrodes; with the latter, hydrogen gas is generated, but it emanates from the reduction of water and not from CO2. Only one electrode material, zerovalent copper, can spawn, in greater-than-trace quantities, a variety of species that are mor...
Source: Catalysis Today - Category: Chemistry Source Type: research
Severe carbon monoxide (CO) poisoning causes fulminant deaths in common environment as well as neurological sequelae to survivors. Prevention of delayed neurological syndrome (DNS) after exposure to CO, the most important sequela, is based up to date on hy...
Source: SafetyLit - Category: International Medicine & Public Health Tags: Economics of Injury and Safety, PTSD, Injury Outcomes Source Type: news
Background: Carbon Monoxide (CO) poisoning is a frequent cause of intoxication. However, CO poisoning incidence is globally underreported, as well as its features, especially in Italy. The aim of this study was to investigate such characteristics of...
Source: SafetyLit - Category: International Medicine & Public Health Tags: Economics of Injury and Safety, PTSD, Injury Outcomes Source Type: news
Chemical Research in ToxicologyDOI: 10.1021/acs.chemrestox.9b00462
Source: Chemical Research in Toxicology - Category: Toxicology Authors: Source Type: research
The Journal of Organic ChemistryDOI: 10.1021/acs.joc.9b03217
Source: The Journal of Organic Chemistry - Category: Chemistry Authors: Source Type: research
AbstractIn systemic sclerosis (SSc) therapeutic efforts are often directed to prevent progressive respiratory impairment, but it is unclear to what extent changes in pulmonary function tests (PFTs) are associated with health-related quality of life (HRQoL). The aim of our study is to evaluate how modifications in PFTs contribute to longitudinal variations in HRQoL, assessed through the multidimensional questionnaire EQ-5D, in patients with SSc. We included SSc patients with forced vital capacity (FVC%), diffusing capacity of the lungs for carbon monoxide (DLCO%) and EQ-5D assessed in at least two visits. The EQ-5D consists...
Source: Clinical Rheumatology - Category: Rheumatology Source Type: research
Chem. Commun., 2020, Advance Article DOI: 10.1039/C9CC08296D, CommunicationZhengnan Yuan, Xiaoxiao Yang, Ladie Kimberly De La Cruz, Binghe Wang Nitro reduction-based fluorescent CO probes only sense ruthenium-based CO donors,CORM-2 andCORM-3, not CO in general. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Chem. Commun. latest articles - Category: Chemistry Authors: Source Type: research
New J. Chem., 2020, Advance Article DOI: 10.1039/C9NJ05089B, PaperSk Safikul Islam, Sk Riyajuddin, Rostam Ali Molla, Nasima Yasmin, Kaushik Ghosh, Sk. Manirul Islam POP-palladium(II) was synthesized for thein situ carbonylation of aryl iodides and secondary cyclic amine to the respective α-ketoamides. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - New J. Chem. latest articles - Category: Chemistry Authors: Source Type: research
Abstract Recently, several arylnitro-based fluorescent CO probes have been reported. The design was based on CO's ability to reduce an arylnitro group for fluorescence turn-on. In this work, we assessed the response of three published arylnitro-based fluorescent CO probes, namely COFP, LysoFP-NO2, and NIR-CO toward CO from various sources. We found that only ruthenium-based CO releasing molecules (CO-RMs) were able to turn on the fluorescence while pure CO gas and CO from other sources did not turn-on the probe in the absence of ruthenium. Further experiments with different ruthenium complexes indicate that the re...
Source: Chemical Communications - Category: Chemistry Authors: Tags: Chem Commun (Camb) Source Type: research
ConclusionsDecrease in the rates of perioperative outcomes parallels improvements in patient selection and perioperative management of early stage NSCLC resection patients. Predictors of pulmonary complication could be used to improve selection criteria for surgery and to reduce the incidence of pulmonary complication in these patients.
Source: The Annals of Thoracic Surgery - Category: Cardiovascular & Thoracic Surgery Source Type: research
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