Effects of aluminum on the expansion and microstructure of alkali-activated MSWI fly ash-based pastes.

Effects of aluminum on the expansion and microstructure of alkali-activated MSWI fly ash-based pastes.
Chemosphere. 2020 Feb;240:124986
Authors: Tian X, Rao F, León-Patiño CA, Song S
Abstract
Alkaline activation is of great potential in the solidification of municipal solid waste incineration (MSWI) fly ash, but the metallic aluminum in the ash inhibits its application. This work studies the effects of residual metallic aluminum on the expansion and microstructure of alkali-activated MSWI fly ash-based pastes. Based on the results obtained, an optimized preparation process is suggested. Characterizations of the pastes include expansion ratio, morphology (SEM), mechanical strength and microstructure (XRD and FTIR). It is confirmed that MSWI fly ash could be solidified through alkaline activation when using a small amount of coal fly ash to adjust the reactive silica and aluminum ratios. In the optimized preparation, sodium hydroxide was added separately, so that expansion in the pastes was significantly mitigated, the formation of geopolymer gel was improved and the compressive strength of the pastes increased.
PMID: 31726592 [PubMed - in process]

Source: Chemosphere - November 17, 2019 Category: Chemistry Authors: Tian X, Rao F, León-Patiño CA, Song S Tags: Chemosphere Source Type: research