Pentacoordinate silicon compounds based on 2,2′-Dihydroxyazobenzene ligand

Publication date: Available online 22 October 2019Source: Journal of Organometallic ChemistryAuthor(s): Anastasiya S. Soldatenko, Irina V. Sterkhova, Nataliya F. LazarevaAbstractThe preparation and structures of 6,6-diorganylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines containing the N→Si intramolecular dative bond are described. The complexes were characterized by NMR (1H, 13C, 29Si), IR and UV spectra. The crystal structures of 6-methyl-6-phenyl- and 6-(chloromethyl)-6-methylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines were determined by X-ray diffraction.Graphical abstract

Source: Journal of Organometallic Chemistry - October 23, 2019 Category: Chemistry Source Type: research