A (2-(Naphthalen-2-yl)phenyl)rhodium(I) Complex formed by a Proposed Intramolecular 1,4-Ortho-to-Ortho ’ Rh Metal-atom Migration and its Efficacy as an Initiator in the Controlled Stereospecific Polymerisation of Phenylacetylene

Dalton Trans., 2019, Accepted Manuscript DOI: 10.1039/C9DT02953B, PaperNicholas Sheng Long Tan, Gareth Nealon, Jason Martin Lynam, Alexandre N. Sobolev, Matthew Ryan Rowles, Mark Ian Ogden, Massimiliano Massi, Andrew B Lowe The synthesis of a novel Rh(I)-aryl complex is detailed and its ability to serve as an initiator in the stereospecific polymerisation of phenylacetylene evaluated. Targeting the Rh(I) species, (2-phenylnaphthalen-1-yl)rhodium(I)(2,5-norbornadiene)tris(para-fluorophenylphosphine), Rh(nbd)(P(4-FC6H4)3)(2-PhNapth),... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - October 18, 2019 Category: Chemistry Authors: Nicholas Sheng Long Tan Source Type: research