Direct synthesis of an anionic 13-vertex closo-cobaltacarborane cluster

Dalton Trans., 2019, Advance Article DOI: 10.1039/C9DT03111A, CommunicationThomas M. Maier, Peter Coburger, Nicolaas P. van Leest, Evamarie Hey-Hawkins, Robert Wolf Reaction of 1,2-bis(diphenylphosphino)-ortho-carborane (L) with [K(thf){(MesBIAN)Co( η4-cod)}] (1,MesBIAN = bis(mesityliminoacenaphthene)diimine, cod = 1,5-cyclooctadiene) affords an anionic 13-vertexcloso-cobaltacarborane cluster (2) in one step. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - October 15, 2019 Category: Chemistry Authors: Thomas M. Maier Source Type: research