Diastereoselective synthesis of -dicarbonyl cyclopropanes via a lanthanide amide-catalysed reaction

Org. Biomol. Chem., 2019, Accepted Manuscript DOI: 10.1039/C9OB00732F, PaperWenxi Sun, Cheng Peng, Zhigang Yao, Fan Xu Lanthanide bis(trimethylsilyl)amides, [(Me3Si)2N]3Ln( μ-Cl)Li(THF)3, were used as efficient catalysts for a one-pot reaction of α-ketoesters, dialkyl phosphite, and activated alkenes to produce -dicarbonyl cyclopropanes in moderate to high yields. The reaction... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research