Copper-mediated cascade radical cyclization of olefins with naphthalenyl iododifluoromethyl ketones

Org. Biomol. Chem., 2019, Accepted Manuscript DOI: 10.1039/C9OB00916G, PaperPeng Peng, Guo Zhi Huang, Yingxin Sun, Xing Wang, Jingjing Wu, Fanhong Wu Copper-mediated radical cyclization of naphthalenyl iododifluoromethyl ketones with olefins was successfully developed to generate series of unprecedented gem-difluorodihydrophenanthrenones, especially 2,2-difluoro-3,4-dihydrophenanthren-1(2H)-one derivatives. This strategy features the use of cheap copper powder... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research