A 3D spin canted coordination polymer with in situ direct CH iodination of 1-H-tetrazole

Publication date: 1 August 2019Source: Inorganica Chimica Acta, Volume 494Author(s): Min-Min Liu, Long Sun, You-Zhu Yu, Ying-Xia Wang, Xian-Ming ZhangAbstractHydrothermal treatment of cupric chloride and tetrazole in the presence of hydroiodic acid generated a spin canted coordination polymer [Cu3(tta)2(Itta)(I0.25-tta)2Cl] (1), (Htta = 1-H-tetrazole, Itta = 5-Iodo-1-H-tetrazole), showing a 3D network constructed from layered [Cu2Cl(tta)2]nn– and chain-like [Cu(Itta)(I0.25tta)2]n2n– moieties linked through expensive Itta groups in situ CH iodinated from cheap Htta.Graphical abstractA 3D spin canted cupric MOF is constructed from the layered [Cu2Cl(tta)2]nn− and chain-like [Cu(Itta)(I0.25tta)2]n2n− motifs linked by 5-Iodo-1-H-tetrazole from in situ C-H iodination of 1-H-tetrazole.

Source: Inorganica Chimica Acta - May 17, 2019 Category: Chemistry Source Type: research