A 3D Spin Canted Coordination Polymer with In Situ Direct C-H Iodination of 1-H-tetrazole

Publication date: Available online 9 May 2019Source: Inorganica Chimica ActaAuthor(s): Min-Min Liu, Long Sun, You-Zhu Yu, Ying-Xia Wang, Xian-Ming ZhangAbstractHydrothermal treatment of cupric chloride and tetrazole in the presence of hydroiodic acid generated a spin canted coordination polymer [Cu3(tta)2(Itta)(I0.25-tta)2Cl] (1), (Htta = 1-H-tetrazole, Itta = 5-Iodo-1-H-tetrazole), showing a 3D network constructed from layered [Cu2Cl(tta)2]nn- and chain-like [Cu(Itta)(I0.25tta)2]n2n- moieties linked through expensive Itta groups in situ C-H iodinated from cheap Htta.Graphical abstract

Source: Inorganica Chimica Acta - May 11, 2019 Category: Chemistry Source Type: research