Comment on "Activation of methane to CH3+: A selective industrial route to methanesulfonic acid"

Díaz-Urrutia and Ott (Reports, 22 March 2019, p. 1326) report a selective conversion of methane to methanesulfonic acid that is proposed to occur by a cationic chain reaction in which CH3+ adds to sulfur trioxide (SO3) to form CH3–S(O)2O+. This mechanism is not plausible because of the solvent reactivity of CH3+, the non-nucleophilicity of the sulfur atom of SO3, and the high energy of CH3–S(O)2O+.

Source: ScienceNOW - May 8, 2019 Category: Science Authors: Roytman, V. A., Singleton, D. A. Tags: Chemistry t-comment Source Type: news