Significant geometry and charge difference between the E_5^(4-) bare clusters of Group 14 Zintl anions and their coordinated form in [E5{M(CO)3}2]4 − (E=Si, Ge, Sn, Pb; M=Cr, Mo, W) complexes

New J. Chem., 2019, Accepted Manuscript DOI: 10.1039/C9NJ00162J, PaperYasin Gholiee, Sadegh Salehzadeh, Shiva Khodaveisi In this paper, at first, the possible structures for E_5^n Zintl ions (E = Si, Ge, Sn, Pb; n = 0, −2, −4) were investigated at BP86/def2-TZVPP and M06-2X/def2-TZVPP levels... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - New J. Chem. latest articles - April 23, 2019 Category: Chemistry Authors: Yasin Gholiee Source Type: research