Lone pair ⋯π interaction versus σ-hole appearance in metal-bonded halogens

CrystEngComm, 2019, Advance Article DOI: 10.1039/C8CE01795F, PaperHamid Reza Khavasi, Narjes Rahimi Three complexes ofN-(2,5-diluorophenyl)-2-pyrazine carboxamide and ZnX2 have been synthesized. The crystal structures reveal that in all three coordination compounds, metal-bound halides have interacted with π systems through a negative electrostatic region. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - CrystEngComm latest articles - April 16, 2019 Category: Chemistry Authors: Hamid Reza Khavasi Source Type: research