Silicone aerogels with tunable mechanical properties obtained via hydrosilylation reaction in supercritical CO2

Publication date: Available online 4 April 2019Source: The Journal of Supercritical FluidsAuthor(s): Igor V. Elmanovich, Tatyana A. Pryakhina, Marat O. Gallyamov, Dmitry A. Migulin, Ivan B. Meshkov, Viktor G. Vasil’ev, Aziz M. MuzafarovAbstractIn the present work various sets of vinyl- and hydride-containing precursors are explored for aerogels synthesis via hydrosilylation route directly in supercritical CO2. The means to control the target mechanical properties of aerogels by changing the precursors composition are proposed. Aerogels with Young’s modulus as low as 3.6 kPa can be obtained using hyperbranched silsesquioxane hydrides, while the use of tetraallylsilane with a linear hydride-containing oligomeric siloxane allows synthesis of aerogels with Young’s modulus in the range of 40 – 124 kPa.Graphical abstract

Source: The Journal of Supercritical Fluids - April 5, 2019 Category: Chemistry Source Type: research