Area-selective electrodeposition of micro islands for CuInSe2-based photovoltaics

Publication date: March 2019Source: Results in Physics, Volume 12Author(s): David Correia, Daniel Siopa, Diego Colombara, Sara Tombolato, Pedro M.P. Salomé, Kamal Abderrafi, Pedro Anacleto, Phillip J. Dale, Sascha SadewasserAbstractFor mass fabrication of highly-efficient photovoltaic modules based on Cu(In,Ga)Se2 (CIGSe) absorber layers the availability and cost of the critical raw materials In and Ga present a potential bottleneck. The micro-concentrator solar cell concept provides a solution by using micro lenses to concentrate incoming sun light on an array of micro-sized CIGSe solar cells. The challenge is to fabricate CIGSe micro islands in exactly the desired positions using only the required material. Here, we analyze the area-selective electrodeposition of CuInSe2 into holes in an insulating SiO2 template layer as a material-efficient fabrication approach. We observe that the deposition process shows a strong dependence on the hole size, with a faster deposition around the hole perimeter. Based on a model developed for electrochemical reactions at ultra-micro electrodes, we develop numerical simulations for the electrochemical deposition process. The simulations consider the changing micro-electrode geometry throughout the deposition process, and provide a reasonable fit to the experimental data. Finally, it is shown that CuInSe2 micro solar cells fabricated by electrodeposition reach efficiencies of 4.8% under 1 sun, providing a proof-of-concept demonstration merit...

Source: Results in Physics - February 26, 2019 Category: Physics Source Type: research