Synthesis of 1,1’-Diacetylferrocene imines via catalytic oxo/imido heterometathesis

Publication date: Available online 14 February 2019Source: Journal of Organometallic ChemistryAuthor(s): Andrey V. Pichugov, Nikolai S. Bushkov, Liudmila V. Erkhova, Pavel A. Zhizhko, Svetlana Ch Gagieva, Dmitry N. Zarubin, Nikolai A. Ustynyuk, Dmitry A. Lemenovskii, Haojie Yu, Li WangAbstractA novel CN bond forming strategy based on oxo/imido heterometathesis between N-sulfinylamines and ketones, catalyzed by a well-defined silica-supported Ti imido complex, was applied to prepare a series of hardly accessible 1,1’-diacetylferrocene ketimines.Graphical abstract

Source: Journal of Organometallic Chemistry - February 15, 2019 Category: Chemistry Source Type: research