Catalytic oxidation at pilot-scale: efficient degradation of volatile organic compounds in gas phase
In this study, a pilot-scale catalytic reactor was developed and the influence of process parameters on toluene degradation were investigated. Inlet gases were heated by electrical resistances and the catalyst employed was a honeycomb shape commercial automotive catalyst (Umicore, model AFT). Toluene degradation higher than 99 % was achieved for several conditions and temperature showed to be the most important process variable for it. For all concentrations, it was observed that when increasing temperature led to a decrease on the space time. At 800 ppmv, varying from 543 K to 633 K, the space time decreased from 0.121 s to 0.08 s, respectively. At 1600 ppmv for the same temperature range, space time was reduced from 0.098 s to 0.040 s, respectively. At 2400 ppmv, varying from 543 K to 633 K, space time decreased from 0.081 s to 0.048 s. The catalytic reactor developed proved to be efficient for VOCs treatment, showing a high potential of application at industrial emission sources.Graphical abstract
Source: Journal of Hazardous Materials - Category: Environmental Health Source Type: research