[( μ2-H)(η2-Ge4)ZnPh2]3−, an edge-on protonated E4 cluster establishing the first three-center two-electron Ge–H–Ge bond

Chem. Commun., 2018, Advance Article DOI: 10.1039/C8CC06843G, CommunicationThomas Henneberger, Wilhelm Klein, Jasmin V. Dums, Thomas F. F ässler The first example of a protonated and a rare example of a metal complex of the tetrahedral tetrel cluster anion [Ge4]4 − was obtained from a solution of K6Rb6Ge17 in liquid ammonia in the presence of ZnPh2 and [18]crown-6. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - October 17, 2018 Category: Chemistry Authors: Thomas Henneberger Source Type: research