Role of chemical reaction and drag force during drop impact gelation process

Publication date: 20 December 2018Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 559Author(s): Krishnayan Haldar, Sudipto ChakrabortyAbstractAn instantaneous chemical reaction and solidification have been experimentally explored during sodium alginate drop impact on calcium chloride liquid pool through a high-speed imaging system. Here, different concentrations of sodium alginate are used to study the effect on gelation process. As soon as the alginate drop touches the calcium chloride pool, a crosslinking polymerization reaction starts under the liquid pool surface. The consequence of crosslinking is rapid formation of calcium alginate gel which denotes instantaneous freezing of liquid drop. The drop impact solidification immediately results in the formation of a strong gel layer in front of it which is having significant role in spherical shape recovery. This layer formation is favoured by increasing sodium alginate concentration in the drop and thus crater growth is hindered also. The initial reaction time which is determined as soon as the drop touches the surface, is found to be dependent on the drop kinetic energy. However, the drop gelation time reduces with drop concentration and it controls the final shape and morphology of gel. Such reduction in gelation time is inferred from the enhanced rate of crosslinking reaction. The motion of liquid drop through liquid pool while interacting with the surroundings influences the drag around th...
Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Category: Chemistry Source Type: research