Examination of disproportionate permeability reduction mechanism on rupture of hydrogels performance

Publication date: 5 January 2019Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 560Author(s): Mahsa Baghban Salehi, Mina Soleimanian, Asefe Mousavi MoghadamAbstractIn this paper, the overall performance of a disproportionate permeability reduction mechanism for a sulfonated polyacrylamide copolymer and the chromium triacetate crosslinker was investigated. A home-built gel filtration system was used for visual inspections and evaluations of the hydrogel performance. The experiments were conducted based on rheological test plans, energy-dispersive X-ray spectroscopy, and scanning electron microscope. Accordingly, quadratic equations based on the polymer and crosslinker concentrations were presented predicting the rupture pressure gradient of the hydrogel and the hydrogel output due to the oil and water injection through the hydrogel. It was indicated that the polymer concentration was the main effect on the rupture pressure gradient of the hydrogel and hydrogel output. Moreover, under constant concentration of crosslinker, increasing polymer concentration showed an increase in rupture pressure gradient and output of the hydrogel due to the increase of elastic modulus of hydrogel network and its strength as a viscoelastic material. As the hydrogel structure illustrated no rupture during the gel filtration experiments, a mechanism presented justifying the disproportionate permeability reduction phenomenon which in that under constant condition, th...

Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects - October 6, 2018 Category: Chemistry Source Type: research