Preparation and physical properties of polypyrrole/zeolite composites

Publication date: Available online 26 September 2018Source: Results in PhysicsAuthor(s): Emma Ziezie Mohd Tarmizi, Hussein Baqiah, Zainal Abidin Talib, Halimah Mohamed KamariAbstractPolypyrrole (PPy′)/zeolite composites were synthesized via chemical oxidation of pyrrole in the presence of zeolite. FeCl3 was used as an oxidant with the FeCl3-to-pyrrole molar ratio (MR) equal to 1. The zeolite contents were 0, 5, 10, 15 and 20 % of the total weight of PPy′. For comparison, pure PPy′′ with FeCl3-pyrrole MR equal to 2 was also synthesized using the same method. The structural and physical properties of the samples were studied using X-rays diffraction (XRD), Fourier transform infrared spectroscopy, field emission electron scanning microscopy, thermogravimetric analysis, van Der Pauw technique and UV-VIS-NIR spectroscopy. The XRD of PPy′/zeolite (5 %) revealed a presence of crystalline nature of zeolite in a spectrum of host amorphous PPy′. The XRD peaks increased, became stronger and shifted slightly to higher 2θ in PPy′/zeolite (10 – 20 %) composites. Compared with PPy′, the composites were denser, more compact and had better thermal stability. The composites conductivity increased while their bandgap tended to reduce with increasing of zeolite. PPy′/zeolite (20 %) composite had the highest conductivity value of 3.6 S cm-1 with an optical bandgap of 2.21 eV. The results showed that zeolite has been incorporated into PPy′ matrix and improved its physical pr...

Source: Results in Physics - October 5, 2018 Category: Physics Source Type: research