New boron reagents for cycloboration of α-olefins into boriranes under Cp2TiCl2 catalysis

Publication date: Available online 11 August 2018Source: Journal of Organometallic ChemistryAuthor(s): Liliya I. Khusainova, Leila O. Khafizova, Tatyana V. Tyumkina, Kirill S. Ryazanov, Natalya R. Popodko, Usein M. DzhemilevAbstractThe one-pot cycloboration of α-olefins (oct-1-ene, dec-1-ene) for a facile access to substituted boriranes has been carried out with the use of alkyl, arylalkyl, and cycloalkyl boron dichlorides (EtBCl2, n-PentBCl2, n-HexBCl2, Ph(CH2)2BCl2, cyclo-OctBCl2, 2-norbornylBCl2) under Cp2TiCl2 catalysis.Graphical abstract

Source: Journal of Organometallic Chemistry - August 12, 2018 Category: Chemistry Source Type: research