Mechanistic insight into sorptive elimination of ibuprofen employing bi-directional activated biochar from sugarcane bagasse: Performance evaluation and cost estimation

Publication date: Available online 11 August 2018Source: Journal of Environmental Chemical EngineeringAuthor(s): Prasenjit Chakraborty, Sumona Show, Soumya Banerjee, Gopinath HalderABSTRACTThe present investigation attempts in separating Ibuprofen (IBP) a pharmaceutical compound from aqueous solution tooled with two different activated form of sugarcane biochar as adsorbent. Differences in adsorption capability of the sugancane biochar were derived after activating its surface both physically and chemically. Operational conditions viz., initial ibuprofen concentration (1-50 mg/L), contact time (0.5-24 hr), temperature (15-40 °C), adsorbent dose (0.033-5 g/L), pH (1-7) and agitation speed (100-200 rpm) were considered for both steam activated biochar (SPAB) and chemically activated biochar (SCAB) for sorptive elimination of IBP. Characterization of the adsorbents were carried out by scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy (EDX), FT-IR spectroscopy and determination of zero point charge (pHPZC). IBP adsorption isotherm study was found to follow both Langmuir and Freundlich isotherm. Uptake capacity of SCAB and SPAB were 13.51 mg/g and 11.90 mg/g respectively. The sorption process obeyed pseudo second order kinetic model in both the cases. Exothermic, spontaneous and feasible nature of IBP adhesion on to SCAB and SPAB were confirmed from thermodynamic analysis. Estimated costs incurred in production of the adsorbents were found to ...
Source: Journal of Environmental Chemical Engineering - Category: Chemistry Source Type: research