Silver-catalyzed stereoselective formation of glycosides using glycosyl ynenoates as donors.

Silver-catalyzed stereoselective formation of glycosides using glycosyl ynenoates as donors.
Chem Commun (Camb). 2018 Jul 18;:
Authors: Dong X, Chen L, Zheng Z, Ma X, Luo Z, Zhang L
Abstract
A silver-catalyzed glycosylation reaction employing readily accessible and stable glycosyl ynenoates is developed. This reaction is mostly high yielding and exhibits varying levels of stereoinversion at the anomeric position. Compared to established and versatile Yu's gold catalysis, this chemistry features the use of substantially cheaper AgNTf2.
PMID: 30019713 [PubMed - as supplied by publisher]

Source: Chemical Communications - July 18, 2018 Category: Chemistry Authors: Dong X, Chen L, Zheng Z, Ma X, Luo Z, Zhang L Tags: Chem Commun (Camb) Source Type: research