Alkali Metal Complexes as Efficient Catalysts for Hydroboration and Cyanosilylation of Carbonyl Compounds

We report here reactions between the N-adamantyliminopyrolyl ligand 2-(AdN=CH)-C4H3NH (L –H) and alkali metal hexamethyldisilazides [MN(SiMe3)2] (M = Li, Na and K) to afford the dimeric [{2-(AdN=CH)-C4H3NLi(THF)}2] (1), [{2-(AdN=CH)-C4H3N}Na(THF)1.5}2] (2) and... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - July 17, 2018 Category: Chemistry Authors: Tarun Kanti Kanti Panda Source Type: research