An unconventional method for measuring the Tc L3-edge of technetium compounds

Tc L3-edge XANES spectra have been collected on powder samples of SrTcO3 (octahedral Tc4+) and NH4TcO4 (tetrahedral Tc7+) immobilized in an epoxy resin. Features in the Tc L3-edge XANES spectra are compared with the pre-edge feature of the Tc K-edge as well as other 4d transition metal L3-edges. Evidence of crystal field splitting is obvious in the Tc L3-edge, which is sensitive to the coordination number and oxidation state of the Tc cation. The Tc L3 absorption edge energy difference between SrTcO3 (Tc4+) and NH4TcO4 (Tc7+) shows that the energy shift at the Tc L3-edge is an effective tool for studying changes in the oxidation states of technetium compounds. The Tc L3-edge spectra are compared with those obtained from Mo and Ru oxide standards with various oxidation states and coordination environments. Most importantly, fitting the Tc L3-edge to component peaks can provide direct evidence of crystal field splitting that cannot be obtained from the Tc K-edge.

Source: Journal of Synchrotron Radiation - October 1, 2014 Category: Physics Authors: Blanchard, P.E.R.Reynolds, E.Kennedy, B.J.Ling, C.D.Zhang, Z.Thorogood, G.Cowie, B.C.C.Thomsen, L. Tags: XANES Tc L3-edge technetium oxides radioactive materials crystal field splitting research papers Source Type: research