Unusual rearrangement of an N-heterocyclic carbene via a ring-opening and ring-closing process

Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC03589J, CommunicationChu-Fan Yang, Taotao Lu, Xue-tai Chen, Zi-Ling Xue Reaction of a pentadentate NHC ligand precursor with Ni(OAc)2 ∙4H2O or Pd(OAc)2 in the presence of a base yields four-coordinate square-planar Ni(II) and Pd(II) complexes with an unusual ligand generated in-situ.... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - June 20, 2018 Category: Chemistry Authors: Chu-Fan Yang Source Type: research