Unsupported Metal Silyl Ether Coordination

Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC04517H, CommunicationJuergen Pahl, Holger Elsen, Alexander Friedrich, Sjoerd Harder Simple silyl ethers like O(SiMe3)2 are in contrast to normal ethers inert to metal bonding, however, a "naked", highly Lewis-acidic, cationic Mg species enforces complexation. DFT calculations indicate that agostic... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - June 19, 2018 Category: Chemistry Authors: Juergen Pahl Source Type: research