Catalyst-controlled switchable reaction of [small beta]-keto acids to silyl glyoxylates

Org. Biomol. Chem., 2018, Accepted Manuscript DOI: 10.1039/C8OB00740C, PaperMan-Yi Han, Hong Pan, Jing Lin, Wei Li, Pinhua Li, Lei Wang A catalyst-controlled switchable reaction of [small beta]-keto acids to silyl glyoxylate was developed under mild conditions, yielding two distinct products in good yields. Compared to decarboxylative addition-Brook rearrangement, the decarboxylative addition... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research