Ultrasound-assisted Suzuki-Miyaura reaction catalyzed by Pd@Cu2(NH2-BDC)2(DABCO)

Publication date: Available online 2 May 2018 Source:Journal of Organometallic Chemistry Author(s): Leila Panahi, M. Reza Naimi-Jamal, Javad Mokhtari The highly porous metal–organic framework Cu2(NH2-BDC)2 (DABCO) (BDC = 1,4-benzenedicarboxilic acid, and DABCO = diazabicyclooctane) loaded with palladium (Pd@Cu-MOF) was found to be an effective catalyst for Suzuki C-C cross coupling accelerated with ultrasonic irradiation. The structure of the catalyst was investigated by EDX (Energy-dispersive X-ray spectroscopy), TGA (Thermogravimetric analysis), FE-SEM (Field Emission Scanning Electron Microscope), TEM (Transmission electron microscopy), XRD (X-ray powder diffractometery), ICP (Inductively coupled plasma), and BET (Brunauer–Emmett–Teller) methods. It was recoverable and reusable for at least four consecutive reactions. Graphical abstract
Source: Journal of Organometallic Chemistry - Category: Chemistry Source Type: research