Control of the Spin Dynamics of Single-Molecule Magnets using a Quasi One-Dimensional Arrangement.

Control of the Spin Dynamics of Single-Molecule Magnets using a Quasi One-Dimensional Arrangement.
Angew Chem Int Ed Engl. 2018 Apr 17;:
Authors: Katoh K, Yamashita S, Yasuda N, Kitagawa Y, Breedlove BK, Nakazawa Y, Yamashita M
Abstract
Magnetic dipole interactions are dominate in quasi one-dimensional (1D) molecular magnetic materials, in which TbNcPc units (Tb3+ = terbium(III) ion, Nc = naphthalocyaninato, Pc = phthalocyaninato) adopt a structure similar to TbPc₂ single-molecule magnets (SMMs). The magnetic properties of the [TbNcPc]0/+ (neutral 1 and cationic 2) with 1D structures are significantly different than those of a magnetically diluted sample (3). In particular, the magnetic relaxation time (τ) of 2 in the low temperature region is five orders of magnitude slower than that of 3. Furthermore, the coercivity (HC) of 2 remained up to about 20 K. The single ion anisotropy of Tb3+ with a 1D structure, the magnetic dipole interactions acting among molecules determines the direction of the magnetic properties. These results show that the spin dynamics can be improved by manipulating the arrangement of SMMs in the solid state.
PMID: 29665263 [PubMed - as supplied by publisher]

Source: Angewandte Chemie - April 17, 2018 Category: Chemistry Authors: Katoh K, Yamashita S, Yasuda N, Kitagawa Y, Breedlove BK, Nakazawa Y, Yamashita M Tags: Angew Chem Int Ed Engl Source Type: research