Colloid ‐Interface‐Assisted Laser Irradiation of Nanocrystals Superlattices to be Scalable Plasmonic Superstructures with Novel Activities

Abstract
High‐efficient charge and energy transfer between nanocrystals (NCs) in a bottom‐up assembly are hard to achieve, resulting in an obstacle in application. Instead of the ligands exchange strategies, the advantage of a continuous laser is taken with optimal wavelength and power to irradiate the film‐scale NCs superlattices at solid–liquid interfaces. Owing to the Au‐based NCs' surface plasmon resonance (SPR) effect, the gentle laser irradiation leads the Au NCs or Au@CdS core/shell NCs to attach each other with controlled pattern at the interfaces between solid NCs phase and liquid ethanol/ethylene glycol. A continuous wave 532 nm laser (6.68–13.37 W cm−2), to control Au‐based superlattices, is used to form the monolayer with uniformly reduced interparticle distance followed by welded superstructures. Considering the size effect to Au NCs' melting, when decreasing the Au NCs size to ≈5 nm, stronger welding nanostructures are obtained with diverse unprecedented shapes which cannot be achieved by normal colloidal synthesis. With the help of facile scale‐up and formation at solid–liquid interfaces, and a good connection of crystalline between NCs, the obtained plasmonic superstructured films that could be facilely transferred onto different substrates exhibit broad SPR absorption in the visible and near‐infrared regime, enhanced electric conductivities, and wide applications as surface enhanced Raman scattering (SERS)‐active substrates.

Colloid...

Source: Small - February 12, 2018 Category: Nanotechnology Authors: Liu Huang, Xiaodong Wan, Hongpan Rong, Yuan Yao, Meng Xu, Jia Liu, Muwei Ji, Jiajia Liu, Lan Jiang, Jiatao Zhang Tags: Full Paper Source Type: research