Stereocontrolled Glycoside Synthesis by Activation of Glycosyl Sulfone Donors with Scandium(III) triflate

Org. Biomol. Chem., 2017, Accepted Manuscript DOI: 10.1039/C7OB02792C, PaperAmandine Xolin, Romain Losa, Aicha Kaid, Cedric Tresse, Jean-Marie Beau, Francois-Didier Boyer, Stephanie Norsikian The activation of aryl glycosyl sulfone donors has been achieved using scandium(III) triflate and has led to the selective preparation of [small alpha]-mannosides resulting from a post-glycosylation anomerization. The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research