Highly Selective Manganese(I)/Lewis Acid Cocatalyzed Direct C −H Propargylation Using Bromoallenes

AngewchemHighly Selective Manganese(I)/Lewis Acid Cocatalyzed Direct C −H Propargylation Using Bromoallenes: A manganese(I)/Lewis acid cocatalyzed direct C −H propargylation with high selectivity has been developed. BPh3 was discovered to not only promote the reactivity, but also enhance the selectivity. Secondary,...

Source: Organometallic Current - December 11, 2017 Category: Chemistry Tags: Mn catalyzed Propargylation Source Type: blogs