Manganese(I) ‐Catalyzed Regio‐ and Stereoselective 1,2‐Diheteroarylation of Allenes: Combination of C−H Activation and Smiles Rearrangement

AngewchemManganese(I) ‐Catalyzed Regio‐ and Stereoselective 1,2‐Diheteroarylation of Allenes: Combination of C−H Activation and Smiles Rearrangement: Heteroarenes are important structural motif in functional molecules. A MnI ‐catalyzed 1,2‐diheteroarylation of allenes via a C−H activation/Smiles rearrangement cascade is presented. The reaction occurred...

Source: Organometallic Current - July 6, 2017 Category: Chemistry Tags: Arylation Difunctionalization Mn catalyzed Source Type: blogs