Air ‐Stable Manganese(I)‐Catalyzed C−H Activation for Decarboxylative C−H/C−O Cleavages in Water
AngewchemAir ‐Stable Manganese(I)‐Catalyzed C−H Activation for Decarboxylative C−H/C−O Cleavages in Water: The decarboxylative C −H/C−O functionalization was accomplished by air‐ and water‐tolerant manganese(I) catalysis. The versatile C−H allylation occurred by facile organometallic C−H metalation on indoles, arenes, amino acids and synthetically meaningful aryl ketimines with ample substrate scope and high leve ls of chemo-, site- and regio-selectivity.
Source: Organometallic Current - Category: Chemistry Tags: C-H Activation C-O Bond Cleavage Decarboxylation Mn catalyzed Source Type: blogs