Interaction of ordinary Portland cement and Opalinus Clay: dual porosity modelling compared to experimental data

Publication date: Available online 18 January 2017 Source:Physics and Chemistry of the Earth, Parts A/B/C Author(s): A. Jenni, T. Gimmi, P. Alt-Epping, U. Mäder, V. Cloet Interactions between concrete and clays are driven by the strong chemical gradients in pore water and involve mineral reactions in both materials. In the context of a radioactive waste repository, these reactions may influence safety-relevant clay properties such as swelling pressure, permeability or radionuclide retention. Interfaces between ordinary Portland cement and Opalinus Clay show weaker, but more extensive chemical disturbance compared to a contact between low-pH cement and Opalinus Clay. As a consequence of chemical reactions porosity changes occur at cement-clay interfaces. These changes are stronger and may lead to complete pore clogging in the case of low-pH cements. The prediction of pore clogging by reactive transport simulations is very sensitive to the magnitude of diffusive solute fluxes, cement clinker chemistry, and phase reaction kinetics. For instance, the consideration of anion-depleted porosity in clays substantially influences overall diffusion and pore clogging at interfaces. A new concept of dual porosity modelling approximating Donnan equilibrium is developed and applied to an ordinary Portland cement – Opalinus Clay interface. The model predictions are compared with data from the cement-clay interaction (CI) field experiment in the Mt Terri underground rock laboratory ...
Source: Physics and Chemistry of the Earth, Parts ABC - Category: Science Source Type: research