Thermal kinetics of PFAS and precursors in soil: Experiment and surface simulation in temperature-time plane

Chemosphere. 2023 Jan 28:138012. doi: 10.1016/j.chemosphere.2023.138012. Online ahead of print.ABSTRACTPer- and polyfluoroalkyl substances (PFAS) are chemically and thermally stable due to the presence of carbon-fluorine (C-F) bond in their molecular structures, hence have been previously formulated as firefighting ingredients. During the firefighting process, however, owing to the high temperature, PFAS can be potentially degraded, particularly for PFAS precursors that contain non-C-F bonds, which is studied herein by exposing PFAS-contaminated soil in a muffle furnace oven. Different temperatures and time intervals are applied to the real soil sample to mimic the firing process and to evaluate the degradation and conversion of PFAS. This thermal treatment can not only degrade precursors (e.g. 6:2 fluorotelomer sulphonate), but also degrade perfluoroalkyl carboxylates (PFCA, e.g. perfluorooctanoic acid PFOA) and perfluoroalkyl sulfonates (PFSA, e.g. perfluorooctane sulfonate PFOS). The concentration dependence of the PFAS on temperature and time is fitted using a 2D Gaussian surface to simulate the complex thermal kinetic, and to compare with the traditional approach such as thermogravimetric analysis (TGA) (1D dependence on temperature only). The 2D simulation can directly visualise the thermal kinetic of individual or sum PFAS in the complex temperature-time plane, which depends on the sample background and particularly on the coexist PFAS precursors. Overall, this study p...

Source: Chemosphere - January 31, 2023 Category: Chemistry Authors: Md Al Amin Yunlong Luo Annette Nolan Megharaj Mallavarapu Ravi Naidu Cheng Fang Source Type: research